The atmosphere is made up of 79% N2 and 20% O2.  To apply rotational or vibrational spectroscopy formulae to these diatomic molecules, you will need to use the reduced mass, given by:

 

A. Calculate the reduced mass for both N2 and O2 in kilograms.

     

 

 

Reduced mass for oxygen = ______________________.

 

Reduced mass for nitrogen = ______________________.

 

B. Given the rotational constant  = 1.99 cm-1 for N2 and 1.45 cm-1 for O2 determine the bond length of each molecule.

 

 

Bond length for oxygen = ______________________.

 

Bond length for nitrogen = ______________________.

 

C. Calculate the intensity of the J=0 à J=1 transition in the rotational spectra of N2.

 

 

 

Microwave absorption intensity for nitrogen = ______________________.